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Nitrile rubber O-rings

What Are Buna-N O-Rings?

KODA-nitrile-o-ring

Buna-N O-rings, also known as Nitrile Rubber O-rings or NBR O-rings, are among the most widely used sealing solutions in industrial equipment, hydraulic systems, fuel handling applications, and general machinery.

Manufactured from a synthetic copolymer of acrylonitrile (ACN) and butadiene, NBR offers an exceptional balance of:

  • Oil resistance
  • Mechanical strength
  • Abrasion resistance
  • Cost efficiency
  • Processing flexibility

Because of this combination, Buna-N remains the default sealing material for countless OEM and maintenance applications worldwide. NBR is especially valued for its resistance to petroleum-based oils and fuels while remaining relatively economical compared with premium elastomers such as FKM or FFKM.

Why Buna-N Is the Most Commonly Used O-Ring Material

Many sealing materials excel in one specific area.

NBR succeeds because it provides balanced performance across multiple operating conditions.

Key Benefits

✓ Excellent resistance to mineral oils

✓ Good fuel compatibility

✓ Strong wear resistance

✓ Reliable compression set performance

✓ Wide availability

✓ Cost-effective production

✓ Suitable for both static and dynamic seals

For hydraulic equipment, gearboxes, pumps, pneumatic systems, and industrial machinery, NBR is often the first material engineers evaluate.

Understanding NBR Polymer Chemistry

The performance of a Buna-N O-ring is largely determined by the amount of acrylonitrile (ACN) incorporated into the polymer chain.

Typical ACN content ranges from approximately 18% to 50%. Lower ACN improves flexibility at low temperatures, while higher ACN increases resistance to fuels and petroleum-based fluids. Standard industrial NBR compounds commonly contain around 34% ACN.

Low ACN NBR (18–25%)

Advantages:

  • Better flexibility
  • Improved low-temperature sealing
  • Reduced brittleness

Recommended for:

  • Outdoor equipment
  • Cold-weather hydraulic systems
  • Refrigeration applications

Medium ACN NBR (30–36%)

Advantages:

  • Balanced performance
  • Good oil resistance
  • Versatile operating range

Recommended for:

  • General industrial equipment
  • Hydraulic systems
  • Pneumatic machinery

High ACN NBR (40–50%)

Advantages:

  • Improved fuel resistance
  • Better solvent resistance
  • Lower fluid permeation

Recommended for:

  • Fuel systems
  • Oil processing equipment
  • Petroleum handling applications

Standard Temperature Range of NBR O-Rings

Typical operating range:

-40°C to +120°C

Special formulations can extend performance beyond standard limits.

However, prolonged exposure above 120°C generally accelerates:

  • Hardening
  • Compression set
  • Loss of elasticity

For temperatures above 150°C, FKM or FFKM materials are usually preferred.

Sulfur-Cured vs Peroxide-Cured NBR

One of the most overlooked factors in O-ring selection is the curing system.

Global O-Ring highlights two primary cure technologies used in NBR compounds.

Sulfur-Cured NBR

Characteristics:

  • Lower cost
  • Better low-temperature flexibility
  • Easier manufacturing

Best for:

  • General industrial applications
  • Standard hydraulic systems
  • Pneumatic equipment

Peroxide-Cured NBR

Characteristics:

  • Better heat resistance
  • Lower compression set
  • Improved aging resistance

Best for:

  • Long service life requirements
  • Elevated temperatures
  • Demanding industrial environments

Although peroxide-cured compounds typically cost more, they often deliver longer maintenance intervals and improved sealing reliability.

Butyronitrile compounds

CompoundsDurometerColorTemp Range (F)Description
N90-B10390Black-40 to +257Peroxide-Cured
N90-C90190Green-4 to +248High visibility
N90-B10290Black-65 to +300Low Temperature
N90-A10190Black-13 to +250General purpose
N80-B10280Black-40 to +212UL 157
N75-F70175Green-40 to +212Metal/X-ray detectable, FDA-Grade
N70-B50270White-40 to +212General purpose, FDA-Grade
N70-B70170Green-40 to +212General Purpose
N70-C40170Blue-40 to +212Metal/X-ray detectable, FDA-Grade
N70-B10270Black-35 to +250General purpose
N70-C10270Black-40 to +221General purpose, low temp resistance
N70-B10670Black-40 to +212NSF 61, FDA
N70-B10370Black-40 to +212UL 157
N70-A10170Black-22 to +250General purpose
N50-B10250Black-40 to +212UL 157
N50-B10150Black-40 to +212General purpose

Chemical Compatibility of Buna-N O-Rings

Excellent Compatibility

NBR performs exceptionally well with:

  • Petroleum oils
  • Diesel fuel
  • Gasoline
  • Hydraulic oils
  • Lubricating greases
  • Vegetable oils
  • Silicone oils
  • Ethylene glycol solutions

These fluid compatibility characteristics make NBR one of the most common sealing materials in automotive and industrial applications.


Limited Compatibility

NBR is generally not recommended for:

  • Ketones
  • Esters
  • Ethers
  • Chlorinated solvents
  • Aromatic hydrocarbons
  • Phosphate ester hydraulic fluids

Using NBR in incompatible media can lead to:

  • Swelling
  • Softening
  • Cracking
  • Premature seal failure

Recommended Hardness Selection

Hardness is measured using Shore A durometer.

70 Shore A

Most common industrial hardness.

Suitable for:

  • Hydraulic systems
  • Pneumatic systems
  • General industrial sealing

80 Shore A

Recommended for:

  • Higher pressure environments
  • Increased extrusion resistance

90 Shore A

Recommended for:

  • Heavy-duty equipment
  • High-pressure hydraulic systems
  • Severe mechanical loads

Engineers often increase hardness when extrusion becomes a concern rather than changing the entire seal design.

Preferred application environment for nitrile rubber O-rings

Performs Well In:

  • Petroleum-based oils and fuels
  • Aliphatic hydrocarbons
  • Vegetable oils
  • Silicone oils and greases
  • Ethylene glycol
  • Dilute acids
  • Water up to 100ºC (212ºF)

Doesn't Perform Well In:

  • Aromatic hydrocarbons
  • Automotive brake fluid
  • Chlorinated hydrocarbons
  • Ketones
  • Ethers
  • Esters
  • Phosphate ester hydraulic fluids
  • Strong acids
  • Ozone, weathering, and sunlight

How to Select the Right Buna-N O-Ring

Before ordering, gather the following information:

Operating Fluid

Examples:

  • Hydraulic oil
  • Diesel fuel
  • Gasoline
  • Grease

Temperature Range

Minimum and maximum operating temperatures.

Pressure Conditions

Determine whether backup rings are necessary.

Dynamic or Static Service

Movement directly affects wear and material selection.

O-Ring Size

Provide:

  • Inside Diameter (ID)
  • Cross Section (CS)
  • Groove dimensions

Regulatory Requirements

Consider:

  • FDA
  • NSF
  • Drinking water approvals
  • Food-contact compliance

Why Many Engineers Still Choose NBR First

Although advanced materials such as FKM, FFKM, AFLAS, and HNBR offer superior performance in specific environments, NBR remains the industry’s workhorse elastomer.

Its combination of:

  • Reliable oil resistance
  • Good mechanical properties
  • Broad size availability
  • Cost effectiveness
  • Proven field performance

makes it one of the most practical sealing materials for everyday industrial applications.

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